Step 1) Check the user status
select USERNAME,ACCOUNT_STATUS,LOCK_DATE,EXPIRY_DATE,PROFILE from dba_users where USERNAME='SYSMAN';
Step 2) Fetch the encrypted password for the corresponding user
select name, password from user$ where name='SYSMAN';
Step 3) Alter the user sysman and set the above encrypted password
alter user SYSMAN identified by values '447B729161192C24' account unlock;
Step 4) Check the user status and try to login using clear text password that your using previously.
select USERNAME,ACCOUNT_STATUS,LOCK_DATE,EXPIRY_DATE,PROFILE from dba_users where USERNAME='SYSMAN';